Corrosion Inhibition Performance of Whey Protein-Derived Inhibitors for Low Carbon and Dead Mild Steels in1M Hydrochloric Acid
DOI:
https://doi.org/10.56294/sctconf2024849Keywords:
Corrosion Inhibition, Whey Protein, Low Carbon Steel, Dead Mild Steel, Hydrochloric AcidAbstract
This research investigates the corrosion inhibition capabilities of BCAA-derived inhibitors for low-carbon steels and dead mild carbon steels with distinct carbon contents when exposed to a 1M HCL solution. The effectiveness of the inhibitors was evaluated by measurements of weight loss and polarization. The study revealed that at a concentration of 10 grams, the weighing method showed that the BCAA inhibitor showed protection effectiveness (87 percent) at 313 K for low carbon steel and (89 percent) effectiveness at 303 K for dead carbon steel. Using a concentration of 15 g, the polarization method showed inhibitory activity of (96 percent) at 313 K for low-carbon steel and (96 percent) at 303 K for dead light carbon steel. These results indicate that the inhibition efficiency is affected by the carbon content. Samples were subjected to scanning electron microscopy (SEM) and optical microscope analysis before and after adding the inhibitor. When examined using FTIR spectroscopy, BCAA showed significant efficiency as a corrosion inhibitor for steel alloys immersed in acidic conditions
References
1. Mustafa, A. M., F. F. Sayyid, N. Betti, L. M. Shaker, M. M. Hanoon, A. A. Alamiery, A. A. H. Kadhum, and M. S. Takriff. "Inhibition of mild steel corrosion in hydrochloric acid environment by 1-amino-2-mercapto-5-(4-(pyrrol-1-yl) phenyl)-1, 3, 4-triazole." South African Journal of Chemical Engineering 39, no. 1 (2022): 42-51.
2. Jawad, D. Zinad, R.D. Salim, A.A. Al-Amiery, T.S. Gaaz, M.S. Takriff and A. Kadhum, Synthesis, Characterization, and Corrosion Inhibition Potential of Novel Thiosemicarbazone on Mild Steel in Sulfuric Acid Environment, Coatings, 2019, 9, 729. doi: 10.3390/coatings9110729
3. S. Al-Baghdadi, F. Noori, W.K. Ahmed and A.A. Al-Amiery, Thiadiazole as a potential corrosion inhibitor for mild steel in 1 M HCl, J. Adv. Electrochem., 2016, 2, 67–69.
4. Mustafa, A. M., Z. S. Abdullahe, F. F. Sayyid, M. M. Hanoon, A. A. Al-Amiery, and W. N. R. W. Isahak. "3-Nitrobenzaldehyde-4-phenylthiosemicarbazone as Active Corrosion Inhibitor for Mild Steel in a Hydrochloric Acid Environment." Progress in Color, Colorants and Coatings 15, no. 4 (2022): 285-293.
5. S. Junaedi, A. Al-Amiery, A. Kadihum, A. Kadhum and A. Mohamad, Inhibition effects of a synthesized novel 4-aminoantipyrine derivative on the corrosion of mild steel in hydrochloric acid solution together with quantum chemicalstudies, Int. J. Mol. Sci., 2013, 14, 11915–11928. doi: 10.3390/ijms140611915
6. A. Alamiery, W.N.R.W. Isahak, H.S.S. Aljibori, H.A. Al-Asadi and A.A.H. Kadhum, Effect of the structure, immersion time and temperature on the corrosion inhibition of 4- pyrrol-1-yl-n-(2,5-dimethyl-pyrrol-1-yl)benzoyl amine in 1.0 M HCl solution, Int. J. Corros. Scale Inhib. 2021, 10, no. 2, 700–713. doi: 10.17675/2305-6894-2021-10-2-14
7. W.K. Al-Azzawi, A.J. Al Adily, F.F. Sayyid, R.K. Al-Azzawi, M.H. Kzar, H.N. Jawoosh, A.A. Al-Amiery, A.A.H. Kadhum, W.N.R.W. Isahak and M.S. Takriff, Evaluation of corrosion inhibition characteristics of an N-propionanilide derivative for mild steel in 1 M HCl: Gravimetrical and computational studies, Int. J. Corros. Scale Inhib. 2022, 11, no. 3, 1100–1114. doi: 10.17675/2305-6894-2022-11-3-12
8. Mohamed, M. Taha, S. A. Nawi, A. M. Mustafa, F. F. Sayyid, M. M. Hanoon, A. A. Al-Amiery, A. A. H. Kadhum, and W. K. Al-Azzawi. "Revolutionizing Corrosion Defense: Unlocking the Power of Expired BCAA."
9. Y.M. Abdulsahib, A.J.M. Eltmimi, S.A. Alphabet, M.M. Hanoon, A.A. Al-Amiery, T. Allami and A.A.H. Kadhum, Experimental and theoretical investigations on the inhibition efficiency of N-(2,4-dihydroxytolueneylidene)-4-methylpyridin-2-amine for the corrosion of mild steel in hydrochloric acid, Int. J. Corros. Scale Inhib. 2021, 10, no. 3, 885–899. doi: 10.17675/2305-6894-2021-10-3-3
10. A.K. Khudhair, A.M. Mustafa, M.M. Hanoon, A. Al-Amiery, L.M. Shaker, T. Gazz, A.B. Mohamad, A.H. Kadhum and M.S. Takriff, Experimental and Theoretical Investigation on the Corrosion Inhibitor Potential of N-MEH for Mild Steel in HCl, Prog. Color, Color. Coat. 2022, 15, 111–122. doi: 10.30509/PCCC.2021.166815.1111
11. D.S. Zinad, R.D. Salim, N. Betti, L.M. Shaker and A.A. AL-Amiery, Comparative Investigations of the Corrosion Inhibition Efficiency of a 1-phenyl-2-(1- phenylethylidene)hydrazine and its Analog Against Mild Steel Corrosion in Hydrochloric Acid Solution, Prog. Color, Color. Coat. 2022, 15, 53–63. doi: 10.30509/pccc.2021.166786.1108
12. R.D. Salim, N. Betti, M. Hanoon and A.A. Al-Amiery, 2-(2, 4-Dimethoxybenzylidene)- N-Phenylhydrazinecarbothioamide as an Efficient Corrosion Inhibitor for Mild Steel in Acidic Environment, Prog. Color, Color. Coat. 2021, 15, 45–52. Doi: 10.30509/pccc.2021.166775.1105.
13. A. Mustafa, F. Sayyid, N. Betti, M. Hanoon, A. Al-Amiery, A. Kadhum and M. Takriff, Inhibition Evaluation of 5-(4-(1H-pyrrol-1-yl)phenyl)-2-mercapto-1,3,4-oxadiazole for the Corrosion of Mild Steel in an Acid environment: Thermodynamic and DFT Aspects, Tribologia, 2021, 38, 39–47. doi: 10.30678/fjt.105330
14. A. Alamiery, W.N.R.W. Isahak, H. Aljibori, H. Al-Asadi and A. Kadhum, Effect of the structure, immersion time and temperature on the corrosion inhibition of 4-pyrrol-1-yln- (2,5-dimethyl-pyrrol-1-yl)benzoylamine in 1.0 m HCl solution, Int. J. Corros. Scale Inhib. 2021, 10, 700–713. doi: 10.17675/2305-6894-2021-10-2-14
15. A. Alamiery, E. Mahmoudi and T. Allami, Corrosion inhibition of low-carbon steel in hydrochloric acid environment using a Schiff base derived from pyrrole: gravimetric and computational studies, Int. J. Corros. Scale Inhib. 2021, 10, 749–765. doi: 10.17675/2305-6894-2021-10-2-17
16. Sayyid, Firas F., Ali M. Mustafa, Mahdi M. Hanoon, Lina M. Shaker, and Ahmed A. Alamiery. "Corrosion Protection Effectiveness and Adsorption Performance of Schiff Base-Quinazoline on Mild Steel in HCl Environment." Corrosion Science and Technology 21, no. 2 (2022): 77-88.
17. Mustafa, A. M., F. F. Sayyid, N. Betti, M. M. Hanoon, Ahmed Al-Amiery, A. A. H. Kadhum, and M. S. Takriff. "Inhibition Evaluation of 5-(4-(1H-pyrrol-1-yl) phenyl)-2-mercapto-1, 3, 4-oxadiazole for the Corrosion of Mild Steel in an Acidic Environment: Thermodynamic and DFT Aspects." Tribologia-Finnish Journal of Tribology 38, no. 3− 4 (2021): 39-47.
18. A.Z. Salman, Q.A. Jawad, K.S. Ridah, L.M. Shaker and A.A. Al-Amiery, Selected BISThiadiazole: Synthesis and Corrosion Inhibition Studies on Mild Steel in HCL Environment, Surf. Rev. Lett., 2020, 27, 2050014. doi: 10.1142/S0218625X20500146
19. A. Fouda, A. Al-Sarawy and E. El-Katori, Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution, Eur. J. Chem., 2010, 1, no. 4, 312–318. doi: 10.5155/eurjchem.1.4.312-318.105
20. Sayyid, Firas F., Ali M. Mustafa, Mahdi M. Hanoon, Lina M. Shaker, and Ahmed A. Alamiery. "Corrosion Protection Effectiveness and Adsorption Performance of Schiff Base-Quinazoline on Mild Steel in HCl Environment." Corrosion Science and Technology 21, no. 2 (2022): 77-88.
21. S. Al-Baghdadi, A. Al-Amiery, T. Gaaz and A. Kadhum, Terephthalohydrazide and isophthalo-hydrazide as new corrosion inhibitors for mild steel in hydrochloric acid: Experimental and theoretical approaches, Koroze Ochre. Mater. 2021, 65, 12–22. doi: 10.2478/kom-2021-0002
22. Abbas, Ahmed S., Bahaa Sami Mahdi, Haider H. Abbas, F. F. Sayyid, A. M. Mustafa, Iman Adnan Annon, Yasir Muhi Abdulsahib, A. M. Resen, M. M. Hanoon, and Nareen Hafidh Obaeed. "Corrosion Behavior Optimization by Nanocoating Layer for Low Carbon Steel in Acid and Salt Media." CORROSION SCIENCE AND TECHNOLOGY 22, no. 1 (2023): 1-9. 23.S.Junaedi, A.A.H. Kadhum, A. Al-Amiery, A.B. Mohamad and M.S. Takriff, Synthesis and characterization of novel corrosion inhibitor derived from oleic acid: 2-Amino-5- Oleyl 1,3,4-Thiadiazol (AOT), Int. J. Electrochem. Sci., 2012, 7, 3543–3554. doi: 10.1016/S1452-3981(23)13976-9
23. S. Al-Baghdadi, F. Hashim, A. Salam, T. Abed, T. Gaaz, A. Al-Amiery, A.H. Kadhum, K. Reda and W. Ahmed, Synthesis and corrosion inhibition application of NATN on mild steel surface in acidic media complemented with DFT studies, Results Phys., 2018, 8, 1178–1184. Doe: 10.1016/j.rinp.2018.02.007.
24. Al-Azzawi, W. K., A. J. Al Adily, F. F. Sayyid, R. K. Al-Azzawi, M. H. Kzar, H. N. Jawoosh, A. A. Al-Amiery, A. A. H. Kadhum, W. N. R. W. Isahak, and M. S. Takriff. "Evaluation of corrosion inhibition characteristics of an N-propionanilide derivative for mild steel in 1 M HCl: Gravimetrical and computational studies." Int. J. Corros. Scale Inhib 11, no. 3 (2022): 1100-1114.
25. Abbass, M. K., K. M. Raheef, I. A. Aziz, M. M. Hanoon, A. M. Mustafa, W. K. Al-Azzawi, A. A. Al-Amiery, and A. A. H. Kadhum. "Evaluation of 2-Dimethylaminopropionamidoantipyrine as a Corrosion Inhibitor for Mild Steel in HCl Solution: A Combined Experimental and Theoretical Study." Progress in Color, Colorants and Coatings 17, no. 1 (2024): 1-10.
26. Khudhair, A. K., A. M. Mustafa, M. M. Hanoon, A. Al-Amiery, L. M. Shaker, T. Gazz, A. B. Mohamad, A. H. Kadhum, and M. S. Takriff. "Experimental and theoretical investigation on the corrosion inhibitor potential of N-MEH for mild steel in HCl." Progress in Color, Colorants and Coatings 15, no. 2 (2022): 111-122.
27. F. F. Sayyied. Et al. (2021), studied the Corrosion Protection Effectiveness and Adsorption Performance of Schiff Base-Quinazoline on Mild Steel in HCL Environment.
28. Sayyid, Firas F., Slafa I. Ibrahim, Mahdi M. Hanoon, A. A. H. Kadhum, and A. A. Al-amiery. "Gravimetric Measurements and Theoretical Calculations of 4-Aminoantipyrine Derivatives as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution: Comparative Studies." Corrosion Science and
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